4.2 Article

A Rapid and Convenient Method for the Synthesis of Aldoximes under Microwave Irradiation Using in situ Generated Ionic Liquids

Journal

JOURNAL OF THE IRANIAN CHEMICAL SOCIETY
Volume 7, Issue 1, Pages 114-118

Publisher

SPRINGER
DOI: 10.1007/BF03245867

Keywords

Oxime; Hydroxylamine hydrochloride; Ionic liquid; Microwave irradiation

Funding

  1. Isfahan University of Technology (IUT), IR Iran
  2. National Institutes of Health, USA [GM 033138, MH 065503, NS 033650]
  3. Center of Excellency in Chemistry Research (IUT)

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We have developed a chemoselective, simple and efficient method for the preparation of aldoximes using microwave irradiation in the presence of tribenzylamine or 1,4-diazabicyclo[2.2.2]octane or 1-benzyl-4-aza-1-azoniabicyclo[2.2.2]octane bromide as bases and useful precursors for in situ generation of ionic liquids.

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