4.7 Article

Effects of wool fibres, ammonium polyphosphate and polymer viscosity on the flammability and mechanical performance of PP/wool composites

Journal

POLYMER DEGRADATION AND STABILITY
Volume 119, Issue -, Pages 167-177

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.polymdegradstab.2015.05.015

Keywords

Wool; Polypropylene; Fire retardant properties; Ammonium polyphosphate; Char

Funding

  1. Ministry of Business, Innovation Employment [UOAX 1004]
  2. Wool Industry Research Limited of New Zealand [CP2013_25]

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In spite of inherent low flammability, wool fibres have not been thoroughly investigated in fire retardant performance of natural fibre polymer composites. In the present work, polypropylene (PP)-short wool fibre composites were produced by compounding in a twin screw extruder and compression moulding. The enhancement of fire retardancy of the composites by adding wool and ammonium polyphosphate (APP) was confirmed by flammability tests. The cone calorimeter and vertical burn tests showed a significant decrease in heat release rate and a direct flame self-extinguishment of composites, respectively. Furthermore, the cone calorimeter experiments and char morphology have revealed that different polymer viscosities in the composites can influence the APP dispersion, leading to different flammability characteristics. The charring tendency of wool contributed to the formation of a rigid char layer and an increase in the amount of residues in the compact micro-structure of PP-wool-APP composites. The effects of wool and APP on mechanical properties have also been reported with improved tensile moduli of PP-wool-APP composites over those of neat PPs. (C) 2015 Elsevier Ltd. All rights reserved.

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