Journal
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
Volume 39, Issue 2-3, Pages 295-304Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2018.09.005
Keywords
Electric field-induced strain; Electrostrictive coefficient; Lead-free; Ferroelectric; BST
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Funding
- National Nature Science Foundation of China [51772239, 51761145024]
- Joint Fund of the Ministry of Education [6141A02033210]
- Natural Science Basis Research Plan in Shaanxi Province of China [2015JM5199, 2017JM5016]
- State Key Laboratory of Solidification Processing in NWPU [SKLSP201709, SKLSP201718]
- Fundamental Research Funds for the Central Universities (XJTU)
- National Basic Research Program of China (973 Program) [2015CB654602]
- Key Scientific and Technological Innovation Team of Shannxi Province [2018TD-024]
- 111 Project [B14040]
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Ferroelectrics with high electrostrictive properties are of great interest in fundamental researches and industrial applications. In this work, the phase structural evolution, dielectric properties as well as electrostrictive properties in barium strontium titanate [(Ba1-xSrx)TiO3, BST] lead-free ferroelectrics with x from 0.05 to 0.4 were investigated in details. High electric field-induced strain (similar to 0.2%) at 60 kV/cm are obtained in x = 0.05 and 0.1 compositions. More importantly, almost purely positive strains with ultra-low hysteresis ( < 8%) determined from bipolar strain-electric field curves are observed in compositions with x from 0.05 to 0.3, suggesting the dominating role of electrostrictive effect. Temperature-insensitive and composition-insensitive longitudinal electrostrictive coefficient Q(33) for BST ceramics with giant values from 0.0409 m(4)/C-2 to 0.0479 m(4)/C-2 is identified. These features suggest that BST ceramics not only possess high electric field-induced strain with ultra-low hysteresis and giant Q(33), but also are good candidates for potential application in high-precision actuator devices.
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