Densification behaviour and microstructural development in undoped yttria prepared by flash-sintering

Conventional sintering of undoped Y2O3 requires temperatures above 1400 degrees C for a few hours. We show that it can be sintered nearly instantaneously to nearly full density at furnace temperature of 1133 degrees C under a DC applied field of 500 V/cm. At 1000 V/cm sintering occurs at 985 degrees C. The FLASH event, when sintering occurs abruptly, is preceded by gradually accelerated field-assisted sintering (FAST). This hybrid behaviour differs from earlier work on yttria-stabilized zirconia where all shrinkage occurred in the flash mode. The microstructure of flash-sintered specimens indicated that densification was accompanied by rapid grain growth. The single-phase nature of flash-sintered Y2O3 was confirmed by high-resolution transmission electron microscopy. The non-linear rise in conductivity accompanying the flash led to Joule heating. It is postulated that densification and grain growth were enhanced by accelerated solid-state diffusion, resulting from both Joule heating and the generation of defects under the applied field. (C) 2013 Elsevier Ltd. All rights reserved.