4.7 Article

Critical energy for photopolymerization of ceramic suspensions in acrylate monomers

Journal

JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
Volume 30, Issue 16, Pages 3273-3282

Publisher

ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2010.08.003

Keywords

Photopolymerization; SiO2; Al2O3; Suspensions; Rapid prototyping

Funding

  1. United States Defense Advanced Research Projects Agency (DARPA) [HR0011-07-1-0034]
  2. Office of Naval Research [N00421-06-1-002]

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The critical energy dose E-c required for photopolymerization of silica and alumina suspensions in acrylate monomers was measured for a large series of suspensions, and contrasted with a model that based on the assumption that E-c is the dose necessary to exhaust the polymerization inhibitors. The major predictions of the model were in good agreement with the data: E-c is inversely proportional to photoinitiator concentration, directly proportional to inert dye concentration, and directly proportional to the concentration of inhibitors. (c) 2010 Elsevier Ltd. All rights reserved.

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