4.6 Article

Efficient enhancement of hydrogen production by Ag/Cu2O/ZnO tandem triple-junction photoelectrochemical cell

Journal

APPLIED PHYSICS LETTERS
Volume 106, Issue 12, Pages -

Publisher

AMER INST PHYSICS
DOI: 10.1063/1.4916224

Keywords

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Funding

  1. Natural Science Foundation of China [11475129, 11175133, 11375134, 51171132]
  2. Program for New Century Excellent Talents in University [NCET-13-0438]
  3. Hubei Provincial Natural Science Foundation [2012FFA042]
  4. Nano Research Program of Suzhou City [ZXG2013003, ZXG201442]

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Highly efficient semiconductor photoelectrodes for solar hydrogen production through photocatalytic water splitting are a promising and challenge solution to solve the energy problems. In this work, Ag/Cu2O/ZnO tandem triple-junction photoelectrode was designed and prepared. An increase of 11 times of photocurrent is achieved in the Ag/Cu2O/ZnO photoelectrode comparing to that of the Cu2O film. The high performance of the Ag/Cu2O/ZnO film is due to the optimized design of the tandem triple-junction structure, where the localized surface Plasmon resonance of Ag and the hetero-junctions efficiently absorb solar energy, produce, and separate electron-hole pairs in the photocathode. (C) 2015 AIP Publishing LLC.

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