Journal
POLYMER CHEMISTRY
Volume 6, Issue 7, Pages 1137-1142Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c4py01223b
Keywords
-
Categories
Funding
- National Science Foundation [DMR-0804878, CHE-0341701, DMR-0414599, CHE-1012636, CHE-1308307]
- Ohio Board of Regents
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1308307] Funding Source: National Science Foundation
- Division Of Materials Research
- Direct For Mathematical & Physical Scien [0804878] Funding Source: National Science Foundation
Ask authors/readers for more resources
In this work we investigated the kinetics of the transesterification of divinyl adipate (DVA) with tetraethylene glycol (TEG) using Candida antarctica lipase B (CALB) as a biocatalyst at 50 degrees C under solventless conditions. We examined the time- dependence of the reactions with various DVA/TEG ratios. Samples were taken at the specified times, and then the composition and end group structures were analyzed by MALDI-ToF mass spectrometry. We found conditions under which polycondensation was minimized and symmetric and asymmetric telechelic TEGs were obtained. Specifically, at DVA/TEG = 1.5 molar ratio 100% of the oligomers had divinyl end groups after 20 minutes reaction time. At DVA/TEG = 3 only vinyl end groups were detected after 5 minutes. HO-(TEG)(n)-Vinyl was maximized at 70% at DVA/TEG 1/1.5 molar ratio at 10 minutes reaction time, while similar to 90% HO-(TEG)(n)-OH was obtained in 20 minutes with TEG excess.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available