4.6 Article

The Effects of Zn Ratio on the Microstructure Electrical Properties of InGaZnO Films

Journal

JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume 158, Issue 10, Pages H949-H954

Publisher

ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.3615534

Keywords

carrier mobility; crystal microstructure; gallium compounds; indium compounds; semiconductor thin films; sputter deposition; transmission electron microscopy; X-ray diffraction; zinc compounds

Funding

  1. Ministry of Knowledge Economy (MKE)
  2. Human Resource Training Project for Strategic Technology

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This study examined the effects of the Zn ratio on the microstructure of InGaZnO (IGZO) films and the device performance of their transistors. IGZO films with various Zn ratios were produced by co-sputtering InGaO and ZnO at different ZnO powers. The combination of transmission electron microscopy (TEM) and X-ray diffraction (XRD) analyses elucidated that as the Zn ratio increased from 0 to 0.69, the microstructure changed from amorphous IGZO to nanocrystalline IGZO and then to columnar ZnO. The dynamic transitions of the microstructure, in turn, profoundly affected the electrical properties including the mobility and carrier concentration. The sample with a mixing ratio of 0.25:0.2:0.55 (In:Ga:Zn) exhibited the best performance with a mobility of nearly 30 cm(2)/V.s. (C) 2011 The Electrochemical Society. [DOI: 10.1149/1.3615534] All rights reserved.

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