Journal
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume 157, Issue 4, Pages A447-A452Publisher
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.3308598
Keywords
battery powered vehicles; electrochemical electrodes; hybrid electric vehicles; lithium compounds; nanostructured materials; nickel compounds; secondary cells
Funding
- U.S. Department of Energy
- FreedomCAR
- Vehicle Technologies Office
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Nanostructured lithium nickel manganese oxides were investigated as advanced positive electrode materials for lithium-ion batteries designated to power plug-in hybrid electric vehicles and all-electric vehicles. The investigation included material characterization and electrochemical testing. In cell tests, the Li(1.375)Ni(0.25)Mn(0.75)O(2.4375) composition achieved high capacity (210 mAh g(-1)) at an elevated rate (230 mA g(-1)), which makes this material a promising candidate for high energy density Li-ion batteries, as does its being cobalt-free and uncoated. The material has spherical morphology with nanoprimary particles embedded in micrometer-sized secondary particles, possesses a multiphase character (spinel and layered), and exhibits a high packing density (over 2 g cm(-3)) that is essential for the design of high energy density positive electrodes. When combined with the Li(4)Ti(5)O(12) stable anode, the cell showed a capacity of 225 mAh g(-1) at the C/3 rate (73 mA g(-1)) with no capacity fading for 200 cycles. Other chemical compositions, Li((1+x))Ni(0.25)Mn(0.75)O((2.25+x/2)) (0.32 < x < 0.65), were also studied, and the relationships among their structural, morphological, and electrochemical properties are reported.
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