Journal
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume 157, Issue 2, Pages F23-F29Publisher
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.3267511
Keywords
electrochemistry; oxidation; polymer structure; polymers; reduction (chemical)
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A polymer based on tetrathionaphthalene (TTN) as a redox active molecular unit is presented. The sulfur-linked TTN polymer, in which TTN segments are covalently linked via thioether, exhibits reversible multiple redox responses and provides an observed capacity of at least 122 mAh g(-1) in an ethylene carbonate:diethyl carbonate (1:3 volume ratio) solution containing 1.0 M LiBF(4) in the potential range from 3.2 to 4.4 V (vs Li/Li(+)) with good cyclability of the potential scan.
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