Journal
JOURNAL OF THE ELECTROCHEMICAL SOCIETY
Volume 156, Issue 3, Pages A176-A180Publisher
ELECTROCHEMICAL SOC INC
DOI: 10.1149/1.3056035
Keywords
-
Ask authors/readers for more resources
The thermal behavior of charged graphite anode and LixCoO2 cathode was investigated focusing on nonflammable electrolytes containing alkyl phosphates as a flame retardant by differential scanning calorimetry. Trimethyl phosphate improved the thermal stability on the cathode side, while a violent exothermic reaction occurred on the anode side. It was demonstrated that the additive technique provides important improvements electrochemically and thermally even in a unique LiBF4/gamma-butyrolactone-based electrolyte containing a reductive phosphate solvent, The flame retardant concept of liquid electrolytes is intrinsically ineffective inside a cell, because the excellent flame retardant, tris(2,2,2-trifluoroethyl) phosphate did not make the anode and cathode more thermally stable. (C) 2009 The Electrochemical Society.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available