4.3 Article

Silver Nitrate-Catalyzed Selective Air Oxidation of Benzylic and Allylic Alcohols to Corresponding Aldehydes or Ketones

Journal

JOURNAL OF THE CHINESE CHEMICAL SOCIETY
Volume 61, Issue 5, Pages 517-520

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/jccs.201300669

Keywords

Oxidation; Silver nitrate; Selectivity; Alcohols

Funding

  1. National Basic Research Program of China (973 Program) [2010CB126101]
  2. National Natural Science Foundation of China [20972052]
  3. Shanghai Key Laboratory of Catalysis Technology for Polyolefins [LCTP-201301]

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The liquid phase selective air oxidation of benzylic and allylic alcohols to corresponding aldehydes or ketones has been achieved in high yields with catalytic amount of AgNO3 and in the presence of Na2CO3.

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