Journal
JOURNAL OF THE CHINESE CHEMICAL SOCIETY
Volume 59, Issue 5, Pages 567-582Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/jccs.201100735
Keywords
Molecular beams; Oriented molecular beams; Photodissociaiton; Roaming mechanism; Methyl formate; Stereodynamics; Steric opacity function; Hexapole state-selector; Non-destructive isomer separation; Reaction control; Reagent self catalyst; Green chemistry
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Funding
- Japanese Ministry of Education, Science, and Culture [2035006, 21550013]
- National Science Council of Taiwan, Republic of China [NSC 99-2113-M-001-025-MY3]
- Grants-in-Aid for Scientific Research [21550013] Funding Source: KAKEN
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Experimental studies on reaction dynamics by use of molecular beams and oriented molecular beams are reviewed in order for looking closer to chemical reactions as well as photodissociations at the molecular level. We discuss about versatility and usefulness of the electrostatic hexapole sate-selector as a non-destructive selector for molecular structure analysis. Some experimental evidences on novel reaction dynamics in photodissociation and stereodynamics are presented followed by concluding remarks and future perspectives for controlling chemical reactions from the point of view of green chemistry, by manipulating molecular orientation without any catalyst nor by applying any external forces like intense electromagnetic field.
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