Journal
JOURNAL OF THE CHINESE CHEMICAL SOCIETY
Volume 55, Issue 6, Pages 1204-1207Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/jccs.200800179
Keywords
Hypervalent iodine; alpha-Thiocynanatoketones; Ionic liquid
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The task-specific ionic liquid (TSIL) and 1-n-butyl-3-methylimidazolium thiocynanate, ([bmim]SCN) were used as the medium as well as the reactant for the synthesis of alpha-thiocynanatoketones by the reaction with (alpha-sulfonyloxy aryl ketones. Significant rate enhancements and improved yields have been observed.
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