4.0 Article

Transition Metal Oxide Nanopowder and Ionic Liquid: an Efficient System for the Synthesis of Diorganyl Selenides, Selenocysteine and Derivatives

Journal

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY
Volume 21, Issue 11, Pages 2079-2087

Publisher

SOC BRASILEIRA QUIMICA
DOI: 10.1590/S0103-50532010001100008

Keywords

synthesis; nanocatalysis; ionic liquids; selenium; selenocysteine; selenides

Funding

  1. CNPq
  2. CAPES
  3. TWAS-CNPq

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We have developed an efficient method for the synthesis of diorganyl selenides and beta-seleno amines using Zn, catalytic amounts of ZnO nanopowder, as a catalyst and ionic liquid as a recyclable solvent. This ZnO/ionic liquid system shows high efficiency in catalyzing these transformations with the formation of the desired products in high yields.

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