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Chemical Constituents of Aristolochia giberti

Journal

JOURNAL OF THE BRAZILIAN CHEMICAL SOCIETY
Volume 20, Issue 9, Pages 1598-1608

Publisher

SOC BRASILEIRA QUIMICA
DOI: 10.1590/S0103-50532009000900006

Keywords

Aristolochia giberti; Aristolochiaceae; (-)-onocera-8,8 '-diol; essential oil; 2-butynedioate

Funding

  1. Fundacao de Amparo a Pesquisa do Estado de Sao Paulo (FAPESP)
  2. Conselho Nacional de Desenvolvimento Cientifico e Tecnologico (CNPq)

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Fourteen compounds were isolated from Aristolochia giberti. These included a new triterperne, (-)-onocera-8,8'-diol. In addition, 3-hydroxypropanoate, acetate, and formate were detected by NMR techniques, which suggests that they are derivatives from 2-butynedioate, which is not detected by H-1 NMR. GC-MS and chemometric analyses of essential oils from stems and leaves showed great similarity between this cultivated species in Brazil and that in Argentina, which allowed us to confirm the species identity and to differentiate the oils according to the plant parts.

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