Journal
POLYHEDRON
Volume 100, Issue -, Pages 313-320Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2015.08.035
Keywords
Porphyrin; Furan; Redox electrolyte; Solar cells; DFT
Categories
Funding
- DST(India)-EPSRC(UK) ('APEX') programme
- EPSRC Supergen programme
- Engineering and Physical Sciences Research Council [EP/M023532/1] Funding Source: researchfish
- EPSRC [EP/M023532/1] Funding Source: UKRI
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A series of four new porphyrin-furan dyads were designed and synthesized by having anchoring group either at meso-phenyl or pyrrole-beta position of a zinc porphyrin based on donor-it-acceptor (D-pi-A) approach. The porphyrin macrocycle acts as donor, furan hetero cycle acts as pi-spacer and either cyanoacetic acid or malonic acid group acts as acceptor. These dyads were fully characterized by UV-Visible, H-1 NMR, MALDI-MS and fluorescence spectroscopies and cyclic voltammetry. Both of the observed and TD-DFT simulated UV-Vis spectra has strong correlation which validate and confirm the synthesized dyads and theoretical method for this type of compounds. Both soret and Q-bands are red shifted in the case of pyrrole-beta substituted dyads. The redox potentials of all four dyads are not altered in comparison with their individual constituents. The dyads were tested in dye sensitized solar cells and found pyrrole-beta substituted zinc porphyrins are showing better performance in comparison with the corresponding meso-phenyl dyads. Optical band gap, Natural bonding, and Molecular bonding orbital (HOMO-LUMO) analysis are in favour of pyrrole-beta substituted zinc porphyrins contrast to meso-phenyl dyads. (C) 2015 Elsevier Ltd. All rights reserved.
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