Journal
POLYHEDRON
Volume 100, Issue -, Pages 400-403Publisher
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.poly.2015.09.004
Keywords
Molybdenum pentachloride; Coordination complexes; Metal reduction; Sulfones; X-ray structure
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The mononuclear complexes MoCl5L (L = 2,5-dihydrothiophene-1,1-dioxide), 1, and MoCl4L2 (L = dimethylsulfone, 2; diethylsulfone, 3; diphenylsulfone, 4) were obtained by the reactions of MoCl5 with the corresponding sulfones at room temperature in dichloromethane, and were characterized by analytical and magnetic data, and by X-ray crystallography in the cases of 1 and 2. The X-ray structure of 1 is the first one ever reported for an adduct of MoCl5 with a carbon-containing species. (C) 2015 Published by Elsevier Ltd.
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