Journal
JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY
Volume 20, Issue 6, Pages 1119-1122Publisher
AMER CHEMICAL SOC
DOI: 10.1016/j.jasms.2009.02.016
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Funding
- Warwick Research Development Fund
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We have used ion mobility-mass spectrometry combined with molecular modeling for the separation and configurational analysis of three low-molecular-weight isomeric organoruthenium anticancer complexes containing ortho-, meta-, or para-terphenyl arene ligands. The isomers were separated using ion mobility based on traveling-wave technology and the experimentally determined collision cross sections were compared to theoretical calculations. Excellent agreement was observed between the experimentally and theoretically derived measurements. (J Am Soc Mass Spectrom 2009, 20, 1119-1122) (C) 2009 American Society for Mass Spectrometry
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