Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 140, Issue 40, Pages 12819-12828Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b05809
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Funding
- National Natural Science Foundation of China [21503185, 51573194]
- NIH [R01-CA215157, 1R01GM128037-01]
- NSF [CHE-1506722]
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Cubic metallacages were arranged into multidimensional (one-, two-, and three-dimensional) suprastructures via multistep assembly. Four new shape-controllable, hybrid metallacages with modified substituents and tunable electronic properties were prepared using dicarboxylate ligands with various substituents (sodium sulfonate, nitro, methoxyl, and amine), tetra-(4-pyridylphenyl) ethylene, and cis-(PEt3)(2)Pt(OTf)(2). The as-prepared metallacages were used as building blocks for further assembly. Diverse suprastructures with tunable emissions (lambda(max) from 451 to 519 nm) and various substituents (-SO3Na, -NO2, -OCH3, and -NH2) were prepared depending on the substituents and solvents used.
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