Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 140, Issue 36, Pages 11206-11209Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b07588
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Funding
- JSPS KAKENHI from MEXT (Japan) [JP15H03777, JP 15K13640]
- Nagoya City University
- JURC
- IRCCS
- KURCA at Kyoto University
- [JP16J05501]
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A stable crystalline 2,5-digermaselenophene was synthesized. In contrast to hitherto reported selenophenes, this digermaselenophene exhibits a transpyramidalized structure, which is due to its electronic properties. The practical utility of this 2,5-digermaselenophene is reflected in its ability to activate dihydrogen and acetylene at room temperature in the absence of a transition-metal complex, and this behavior can be rationalized on the basis of its physicochemical properties, which are characterized by considerable electron-donating and-accepting abilities.
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