Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 140, Issue 32, Pages 10153-10157Publisher
AMER CHEMICAL SOC
DOI: 10.1021/jacs.8b07050
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Funding
- EU FP7 ERC-Co [615954]
- Spanish MINECO [PN MAT2015-65354-C2-1-R]
- Catalan AGAUR [2014 SGR 80]
- CERCA Program/Generalitat de Catalunya
- MINECO through the Severo Ochoa Centers of Excellence Program [SEV-2013-0295]
- Generalitat de Catalunya [2014 BP-B 00155]
- Marie Curie Fellowship, EU
- European Research Council (ERC) [615954] Funding Source: European Research Council (ERC)
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Herein we describe the topological influence of zigzag ligands in the assembly of Zr(IV) metal -organic frameworks (MOFs). Through a transversal design strategy using reticular chemistry, we were able to synthesize a family of isoreticular Zr(IV)-based MOFs exhibiting the bcu-rather than the fcu-topology. Our findings underscore the value of the transversal parameter in organic ligands for dictating MOF architectures.
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