Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 44, Pages 15493-15496Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja509058u
Keywords
-
Categories
Funding
- Clinton Health Access Initiative
- Corning Glass
- Gates Foundation
- NSF [CHE-1152020]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1058957] Funding Source: National Science Foundation
Ask authors/readers for more resources
Ylidenemalononitrile enamines undergo rapid amine exchange followed by a cyclization with primary amines to yield fluorescent products with emission intensities as high as 900 times greater than the starting materials. After identifying the fluorescent species by X-ray crystallography, we demonstrate that the rate of amine exchange is substrate dependent and that by simple structural variation the fluorescence can be tuned over the entire visible spectrum. We further demonstrate their potential application in biomolecule labeling.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available