Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 38, Pages 13174-13177Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja5078365
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Funding
- NSF [Career CHE-1362057, CHE-1228336]
- NSFC [21228204]
- Direct For Mathematical & Physical Scien [1228336] Funding Source: National Science Foundation
- Division Of Chemistry [1228336] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1362057] Funding Source: National Science Foundation
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1619590] Funding Source: National Science Foundation
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Gold-catalyzed oxidative cross-coupling of allcynes to unsymmetrical diynes has been achieved for the first time. A N,N-ligand (1,10-Phen) and PhI(OAc())2 were identified as crucial factors to promote this transformation, giving the desired cross-coupled conjugated diynes in excellent heteroselectivity (>10:1), in good to excellent yields, and with large substrate tolerability.
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