Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 39, Pages 13594-13597Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja507788r
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Funding
- DOE [DE-FG02-13ER16370]
- National Natural Science Foundation of China [21176110]
- Jiangsu Province Natural Science Foundation [BK20141311]
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Anti-Bredt di(amino)carbene supported gold(I) chloride complexes are readily prepared in two steps from the corresponding isocyanide complexes. In the presence of KB(C6F5)(4) as chloride scavenger, they promote the unprecedented hydroarylation reaction of alkenes with N,N-dialkylanilines with high para-selectivity. The latter are challenging arenes for Friedel-Craft reactions, due to their high basicity.
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