Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 5, Pages 1782-1785Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja412606t
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Funding
- Army Research Office [W911NF-12-1-0581]
- Office of Energy Efficiency and Renewable Energy of the U.S. Department of Energy [DE-AC36-08GO28308]
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We report a novel strategy for the controlled synthesis of gold nanoparticles (AuNPs) with narrow size distribution (1.9 +/- 0.4 nm) through NP nucleation and growth inside the cavity of a well-defined three-dimensional, shape-persistent organic molecular cage. Our results show that both a well-defined cage structure and pendant thioether groups pointing inside the cavity are essential for the AuNP synthesis.
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