Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 19, Pages 6884-6887Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja502885c
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Funding
- Department of Defense (NDSEG fellowship to S.M.K.)
- National Science Foundation [CHE-1151563]
- Graduate Research Fellowship to S.M.K.)
- Alfred P. Sloan Foundation
- the David and Lucile Packard Foundation
- the Research Corporation for Science Advancement
- the Camille and Henry Dreyfus Foundation
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A general method for the selective hydrogenation of alkenyl halides to alkyl halides is described. Fluoro, chloro, bromo, iodo, and gem-dihaloalkenes are viable substrates for the transformation. The selectivity of the hydrogenation is consistent with reduction by a hydrogen atom transfer pathway.
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