Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 2, Pages 547-549Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja4129795
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Funding
- Welch Foundation [AX-1730, AX-1593]
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A homochiral microporous hydrogen. bonded organic framework (HOF-2) based on a BINOL derivative has been synthesized and structurally characterized to be a uninodal 6-connected {3(3)5(5)6(6)7} network. This new HOF exhibits not only a permanent porosity with the BET of 237.6 m(2) g(-1) but also, more importantly, a highly enantioselective separation of chiral secondary alcohols with ee value up to 92% for 1-phenylethanol.
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