4.8 Article

Columnar Liquid Crystallinity and Mechanochromism in Cationic Platinum(II) Complexes

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 8, Pages 2952-2955

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja4114352

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Funding

  1. National Science Foundation [DMR-1005810]
  2. Department of Defense NDSEG Fellowship Program [2291100]
  3. Division Of Materials Research
  4. Direct For Mathematical & Physical Scien [1005810] Funding Source: National Science Foundation

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Cationic square planar Pt(II) complexes are reported with high degrees of intermolecular association. These complexes display thermotropic columnar liquid crystalline behavior in spite of having only a single side chain. Crystals undergo mechanochromic transformations that can be reversed with solvent.

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