Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 8, Pages 2966-2969Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja412582k
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Funding
- [24000009]
- [25708008]
- Grants-in-Aid for Scientific Research [25708008] Funding Source: KAKEN
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Proximity between a noninteractive organic substrate and a transition metal (trans-MCl2(PEt3)(2); M = Pd or Pt) is achieved by their co-encapsulation within a synthetic cage, as revealed by X-ray crystallographic analysis and NOESY experiments. Through co-encapsulation with a Pd(II) complex, a terminal alkyne was activated within the cage to give a sigma-alkynylpalladium complex.
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