Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 42, Pages 14642-14645Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja508605a
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Funding
- Ministry of Science and Technology [2012CB821600]
- Natural Science Foundation of China (NSFC) [21390400, 21202171, 21025208]
- Chinese Academy of Sciences, S.L
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We describe the direct construction of all-carbon quaternary stereocenters via a-photoalkylation of beta-ketocarbonyls with high efficacy and enantioselectivities by merging photoredox catalysis and primary amine catalysis. The open-shell photoradical approach enables asymmetric a-alkylations that are difficult under thermal conditions.
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