Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 44, Pages 15469-15472Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja508645j
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Funding
- National Basic Research Program of China (973 Program) [2010CB833300]
- National Natural Science Foundation of China [21025209, 21121062, 21332009]
- Chinese Academy of Sciences
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A novel Pd(0)-catalyzed intramolecular arylative dearomatization of para-aminophenol derivatives is described. In the presence of 1.25 mol % [Pd(C3H5)Cl](2) and 3.75 mol % RuPhos, the arylative dearomatization reaction proceeds smoothly for a broad range of substrates, offering an efficient synthetic route to erythrinane derivatives in excellent yields.
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