Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 38, Pages 13194-13197Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja508165a
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- Scripps Research Institute
- NIH (NIGMS) [2R01GM084019]
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9-Methylacridine was identified as a generally effective ligand to promote a Pd(II)-catalyzed C(sp(3))-H and C(sp(2))-H alkylation of simple amides with various alkyl iodides. This alkylation reaction was applied to the preparation of unnatural amino acids and geometrically controlled tri- and tetrasubstituted acrylic acids.
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