Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 12, Pages 4484-4487Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja500793x
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Funding
- National Natural Science Foundation of China [21371166, 21221061, 21331003]
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The magnetic relaxation dynamics of low-coordinate Dy-III and Er-III complexes, namely three-coordinate ones with an equatorially coordinated triangle geometry and five-coordinate ones with a trigonal bipyramidal geometry, have been exploited for the first time. The three-coordinate Er-based complex is the first equatorially coordinated mononuclear Er-based single-molecule magnet (SMM) corroborating that simple models can effectively direct the design of target SMMs incorporating 4f-elements.
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