4.8 Article

Stepwise Construction of Discrete Heterometallic Coordination Cages Based on Self-Sorting Strategy

Journal

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 8, Pages 2982-2985

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/ja412667t

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Funding

  1. National Science Foundation of China [91122017, 21374019]
  2. Shanghai Science and Technology Committee [13JC1400600, 13DZ2275200, 11QA1400300]
  3. Program for Changjiang Scholars and Innovative Research Team in University [IRT1117]

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A chelation-directed self-sorting synthesis of a series of cationic heterometallic coordination cages (HCCs) with tunable sizes is described. Two complexation modes were found in the cage-forming process. Metal-anchoring host-guest behavior and size-selective in-cage catalytic activities were found for the HCCs.

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