Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 38, Pages 13182-13185Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja507947d
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Funding
- NSF [CHE-1111490]
- National Science Foundation (NSF)-Earth Sciences [EAR-1128799]
- Department of Energy (DOE)-GeoSciences [DE-FG02-94ER14466]
- Division of Chemistry (CHE), NSF [NSF/CHE-1346572]
- U.S. DOE [DE-AC02-06CH11357]
- Division of Materials Research (DMR), NSF [NSF/CHE-1346572]
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1346572] Funding Source: National Science Foundation
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A robust and porous Zr metal organic framework, sal-MOF, of UiO topology was synthesized using a salicylaldimine (sal)-derived dicarboxylate bridging ligand. Postsynthetic metalation of sal-MOP with iron(II) or cobalt(II) chloride followed by treatment with NaBEt3H in THF resulted in Fe- and Co-functionalized MOFs (sal-M-MOF, M = Fe, Co) which are highly active solid catalysts for alkene hydrogenation. Impressively, sal-Fe-MOF displayed very high turnover numbers of up to 145000 and was recycled and reused more than 15 times. This work highlights the unique opportunity of developing MOF-based earth-abundant catalysts for sustainable chemical synthesis.
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