Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 45, Pages 15809-15812Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja508829x
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Funding
- NSERC of Canada
- Canada Research Chair
- NSERC CGS-D2
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Hydrogenation of alkyl and aryl ketones using H-2 is catalytically achieved in 18 examples using 5 mol % B(C6F5)(3) in an ethereal solvent. In these cases the borane and ether behave as a frustrated Lewis pair to activate H-2 and effect the reduction.
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