Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 5, Pages 1778-1781Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja412432k
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Funding
- Centre National de la Recherche Scientifique
- Universite de Toulouse
- Agence Nationale de la Recherche [ANR-10-BLAN-070901]
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Taking advantage of phosphine chelation, direct evidence for oxidative addition of C-sp(2)-X bonds (X = I, Br) to a single gold atom is reported. NMR studies and DFT calculations provide insight into this unprecedented transformation, which gives straightforward access to stable (P,C) cyclometalated gold(III) complexes.
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