Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 30, Pages 10581-10584Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja505455z
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- NIH [GM-59471]
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The reaction of 1,1-bis(pinacolboronate) esters with alkyl halides can be effected by metal alkoxides and provides a strategy for the construction of organo-boronate compounds. The reaction is found to occur by alkoxide-induced deborylation and generation of a boron-stabilized carbanion.
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