Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 38, Pages 13114-13117Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja506034n
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Funding
- A. v. Humboldt foundation
- ERC [SUPRA-DAPT 290585]
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Chiral N-alkyl imines undergo unidirectional rotation induced by light and heat, thus providing a new class of molecular motors. Depending on the conformational flexibility of the stator part (the carbonyl residue) and the nitrogen inversion barrier of the rotor part (the amine residue) in the molecule, the operation mode of the motor can be controlled as either a four- or a two-step cycling motion of the rotor part.
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