Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 21, Pages 7543-7546Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja5019095
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Funding
- Japan Society for the Promotion of Science
- ERATO Kitagawa Integrated Pores Project
- ACCEL Project from the Japan Science and Technology Agency
- Grants-in-Aid for Scientific Research [13F03032, 25870360] Funding Source: KAKEN
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A porous coordination polymer (PCP) has been synthesized employing an organic ligand in which a stable free radical, isoindoline nitroxide, is incorporated. The crystalline PCP possesses one-dimensional channels decorated with the nitroxyl catalytic sites. When O-2 gas or air was used as the oxidant, this PCP was verified to be an efficient, recyclable, and widely applicable catalyst for selective oxidation of various alcohols to the corresponding aldehydes or ketones.
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