Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 40, Pages 13991-13994Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja507799e
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Funding
- National Science Foundation [CHE-1265674, CHE-0840505]
- Direct For Mathematical & Physical Scien [1265674] Funding Source: National Science Foundation
- Division Of Chemistry [1265674] Funding Source: National Science Foundation
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An intramolecular 1,2(alpha)-H migration in a saturated ruthenium stannylene complex, to form a ruthenostannylene complex, involves a reversal of the role for a coordinated stannylene ligand, from that of an electron donor to an acceptor in the transition state. This change in the bonding properties for a stannylene group, with a simple molecular motion, lifts the usual requirement for generation of an unsaturated metal center in migration chemistry.
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