Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 25, Pages 8859-8862Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja502765n
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Funding
- U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences (U.S. DOE-BES) [DE-SC0006937]
- U.S. DOE-BES [DE-SC0001088]
- NSF [1122374, ECS-0335765]
- U.S. DOE, Graduate Fellowship Program [DE-AC05-06OR23100]
- NSF Center for Integrated Quantum Materials (CIQM) [NSF-DMR-1231319]
- U.S. DOE [DE-AC02-98CH10886]
- U.S. DOE by Argonne National Laboratory [DE-AC02-06CH11357]
- U.S. Department of Energy (DOE) [DE-SC0006937] Funding Source: U.S. Department of Energy (DOE)
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Reaction of 2,3,6,7,10,11-hexaaminotriphenylene with Ni2+ in aqueous NH3 solution under aerobic conditions produces Ni-3(HITP)(2) (HITP = 2,3,6,7,10,11-hexaiminotriphenylene), a new two-dimensional metal-organic framework (MOF). The new material can be isolated as a highly conductive black powder or dark blue-violet films. Two-probe and van der Pauw electrical measurements reveal bulk (pellet) and surface (film) conductivity values of 2 and 40 S.cm(-1), respectively, both records for MOFs and among the best for any coordination polymer.
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