Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 39, Pages 13578-13581Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja507853f
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Funding
- Murdock Charitable Trust [200.5265]
- National Science Foundation [CHE-0722319]
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A chiral iron(III)salen complex based on a cis-2,5-diaminobicyclo[2.2.2]octane scaffold catalyzes asymmetric Conia-ene-type cyclization of alpha-functionalized ketones containing an unactivated terminal alkyne and produces an exo-methylenecycloalkane possessing a stereodefined quaternary center.
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