Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 3, Pages 914-917Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja4120852
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- National Science Council of Taiwan [NSC-101-2628-M-001-002-MY3]
- Academia Sinica
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The formation of a hitherto unknown three-coordinate dicationic hydrido boron complex is described. Interestingly, supporting ligand carbodicarbene gave unprecedented reaction with BH3 without using more highly electrophilic Lewis acid precursors. Spectroscopic, crystallographic, and computational analysis was performed to understand the electronic features of these species.
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