Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 44, Pages 15461-15464Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja508094h
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Funding
- University of Bordeaux
- CNRS
- Aquitaine Region
- IUF
- ANR [ANR-12-PDOC-0038]
- NNSF of China [21172084, 20802022]
- Program for New Century Excellent Talents in University of China [NCET-10-040]
- CCNU [CCNU13F006, CCNU14Z01001, CCNU11C01002]
- Agence Nationale de la Recherche (ANR) [ANR-12-PDOC-0038] Funding Source: Agence Nationale de la Recherche (ANR)
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Co/Fe Prussian Blue analogues are known to display both thermally and light induced electron transfer attributed to the switching between diamagnetic {(FeLS)-L-II(mu-CN)(CoLS)-L-III} and paramagnetic {(FeLS)-L-III(beta-CN)(CoHS)-H-II} pairs (LS = low spin; HS = high spin). In this work, a dinuclear cyanido-bridged Co/Fe complex, the smallest {Fe(mu-CN)Co} moiety at the origin of the remarkable physical properties of these systems, has been designed by a rational building-block approach. Combined structural, spectroscopic, magnetic and photomagnetic studies reveal that a metal-to-metal electron transfer that can be triggered in solid state by light, temperature and solvent contents, is observed for the first time in a dinuclear complex
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