Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 8, Pages 3036-3039Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja501142e
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Funding
- NCRR NIH HHS [S10RR025631, S10 RR025631] Funding Source: Medline
- NIGMS NIH HHS [R01 GM090007] Funding Source: Medline
- Direct For Mathematical & Physical Scien [1048804] Funding Source: National Science Foundation
- Division Of Chemistry [1048804] Funding Source: National Science Foundation
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We report the enantiospecific total synthesis of (+)-tubingensin A. Our synthesis features an aryne cyclization to efficiently introduce the vicinal quaternary stereocenters of the natural product and proceeds in only nine steps (longest linear sequence) from known compounds.
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