Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 17, Pages 6223-6226Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja502169d
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Funding
- MEXT [22105005, 24106718, 23685019, 23350041]
- JST (ACT-C)
- Grants-in-Aid for Scientific Research [23350041, 22105005, 24106718, 23685019] Funding Source: KAKEN
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A cationic rhodium(I) catalyst turns 2-silyl-1-alkenylboronate, readily prepared from a terminal alkyne, into the corresponding allylboronate species, which immediately undergoes nucleophilic addition to an aldehyde to give a syn-homoallylic alcohol stereoselectively.
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