Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 48, Pages 16788-16791Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja5105602
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- NIH [GM104180]
- FRQNT
- Eli Lilly
- Boehringer Ingelheim
- Amgen
- Baxter Foundation
- Sloan Foundation
- NATIONAL INSTITUTE OF GENERAL MEDICAL SCIENCES [R01GM104180] Funding Source: NIH RePORTER
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Catalytic amounts of Co(Sal((tBu),(tBu))Cl and organosilane irreversibly isomerize terminal alkenes by one position. The same catalysts effect cycloisomerization of dienes and retrocycloisomerization of strained rings. Strong Lewis bases like amines and imidazoles, and labile functionalities like epoxides, are tolerated.
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