Journal
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
Volume 136, Issue 22, Pages 7797-7800Publisher
AMER CHEMICAL SOC
DOI: 10.1021/ja500666h
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- JST
- ACT-C
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Japan Society for the Promotion of Science for Young Scientists
- Grants-in-Aid for Scientific Research [23350017, 25105729] Funding Source: KAKEN
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We have developed a redox-economical coupling reaction of alcohols and alkynes to form allylic alcohols under mild conditions. The reaction is redox-neutral as well as redox-economical and thus free from any additives such as a reductant or an oxidant. This atom-economical coupling can be applied for the conversion of both aliphatic and benzylic alcohols to the corresponding substituted allylic alcohols in a single synthetic operation.
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